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Diallyl disulphide

Diallyl Disulfide

CAS: 2179-57-9;138540-99-5

Molecular Formula: C6H10S2

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Diallyl disulphide - Names and Identifiers

Name Diallyl Disulfide
Synonyms DADS
Garlicin
Allyl disulfide
Diallyldisulfide
dialkyldisulfide
Diallyl Disulfide
Diallyl disulphide
Disulfide,di-2-propenyl
4,5-Dithia-1,7-octadiene
Disulfide, di-2-propenyl
2-(diphenylphosphanyl)benzaldehyde
3-(prop-2-en-1-yldisulfanyl)prop-1-ene
4,7-dihydroxyhexahydro-2-benzofuran-1(3H)-one
Diallyldisulfide, remainder mainly diallyl sulfide
CAS 2179-57-9
138540-99-5
EINECS 218-548-6
InChI InChI=1/C8H12O4/c9-5-1-2-6(10)7-4(5)3-12-8(7)11/h4-7,9-10H,1-3H2
InChIKey PFRGXCVKLLPLIP-UHFFFAOYSA-N

Diallyl disulphide - Physico-chemical Properties

Molecular FormulaC6H10S2
Molar Mass146.27
Density1.008g/mLat 25°C(lit.)
Boling Point180-195°C(lit.)
Flash Point144°F
JECFA Number572
Water SolubilityInsoluble in water
Vapor Presure1 mm Hg ( 20 °C)
Vapor Density>5 (vs air)
AppearanceTransparent liquid
Colorcolorless to yellow
OdorDiallyl disulfide is an essential odor component of garlic oil.
BRN1699241
Storage Condition2-8°C
SensitiveSensitive to heat and air
Refractive Indexn20/D 1.541(lit.)
MDLMFCD00008656
Physical and Chemical PropertiesLight yellow liquid. The patient presented with special garlic odor, with tear-inducing property. Boiling point 138~139 °c, or 79 °c (2133Pa). Insoluble in water, soluble in most common organic solvents. Natural products are found in raw cabbage, onions, garlic, chives, etc.
UseUsed as food additives, pharmaceutical intermediates

Diallyl disulphide - Risk and Safety

Risk CodesR22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin.
R10 - Flammable
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S37/39 - Wear suitable gloves and eye/face protection
S16 - Keep away from sources of ignition.
S36 - Wear suitable protective clothing.
UN IDsUN 2810 6.1/PG 3
WGK Germany3
RTECSBB1000000
FLUKA BRAND F CODES13
TSCAYes
HS Code29309090
Hazard Class6.1
Packing GroupII

Diallyl disulphide - Reference

Reference
Show more
1. [IF=2.858] Tian-Tian Li et al."Control of pathogenic fungi on Panax notoginseng by volatile oils from the food ingredients Allium sativum and Foeniculum vulgare."LETTERS IN APPLIED MICROBIOLOGY. 2022 Apr 06

Diallyl disulphide - Introduction

Soluble in ethanol, chloroform or ether, insoluble in water. It has a strong garlic flavor and is spicy.
Last Update:2022-10-16 17:14:58

Diallyl disulphide - Reference Information

FEMA2028 | ALLYL DISULFIDE
olfactory threshold (Odor Threshold)0.00022ppm
NIST chemical information Information provided by: webbook.nist.gov (external link)
EPA chemical information Information provided by: ofmpub.epa.gov (external link)
introduction diallyl disulfide is a light yellow liquid and can be used as a food additive and pharmaceutical intermediate.
toxicity GRAS(FEMA).
use limit FEMA(mg/kg): condiment 6.5; Meat 7.0. FDA,§ 172.515(2000): The right amount is limited.
use food spices.
Used as food additive and pharmaceutical intermediate
Production method It is obtained by oxidation of allyl mercaptan and iodine in the presence of ethanol and pyridine.
category toxic substances
toxicity classification highly toxic
acute toxicity oral-rat LD50: 260 mg/kg
flammability hazard characteristics combustible; combustion produces toxic sulfur oxide smoke
storage and transportation characteristics warehouse ventilation and low temperature drying; separate from food raw materials
fire extinguishing agent dry powder, foam, sand, carbon dioxide, mist water
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update:2024-04-09 20:52:54
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Diallyl disulphide
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